{"id":198,"date":"2019-11-15T09:48:49","date_gmt":"2019-11-15T08:48:49","guid":{"rendered":"https:\/\/web.umons.ac.be\/smos\/?p=198"},"modified":"2022-05-24T09:51:06","modified_gmt":"2022-05-24T07:51:06","slug":"new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers","status":"publish","type":"post","link":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/","title":{"rendered":"New paper on the relative quantification of architectural isomeric polymers"},"content":{"rendered":"<figure id=\"attachment_199\" aria-describedby=\"caption-attachment-199\" style=\"width: 758px\" class=\"wp-caption alignnone\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-199\" src=\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg\" alt=\"New paper on the relative quantification of architectural isomeric polymers\" width=\"758\" height=\"541\" srcset=\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg 758w, https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers-300x214.jpg 300w, https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers-30x21.jpg 30w, https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers-60x43.jpg 60w, https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers-360x257.jpg 360w\" sizes=\"auto, (max-width: 758px) 100vw, 758px\" \/><figcaption id=\"caption-attachment-199\" class=\"wp-caption-text\">New paper on the relative quantification of architectural isomeric polymers<\/figcaption><\/figure>\n<p>&nbsp;<\/p>\n<p>New just accepted paper in a special issue about synthetic polymers of <strong>Rapid Communications in Mass Spectrometry<\/strong>, in collaboration with Prof. Scott M. Grayson (Tulane University, New Orleans, US).<\/p>\n<p>In this work, we are investigating the suitability of Ion Mobility Spectrometry-Mass Spectrometry (IMS) for the quantification of two isomers. A cyclic poly(L-lactide) is prepared through photodimerization of its linear homologue. Since IMS can be used to differentiate cyclic-polymer ions from their linear analogues because of their more compact three-dimensional conformation, the present work envisages IMS for the quantification of residual linear polymers within the cyclic polymer sample.<\/p>\n<p>By using the standard addition method to plot calibration curves, the fraction of linear contaminants in the sample is determined. Doing so, unrealistically high values of contamination were measured. These results are explained by an ionization efficiency issue. This work underlines the intrinsic limitations of IMS in the context of the quantification of isomers. Nevertheless, the linear-to-cyclic ratio can be roughly estimated by this method.<\/p>\n<p><a href=\"https:\/\/doi.org\/10.1002\/rcm.8660\">DOI: 10.1002\/rcm.8660<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>In this work, we are investigating the suitability of Ion Mobility Spectrometry-Mass Spectrometry (IMS) for the quantification of two isomers. A cyclic poly(L-lactide) is prepared through photodimerization of its linear homologue. &#8230;<\/p>\n","protected":false},"author":157,"featured_media":199,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[47],"tags":[],"class_list":["post-198","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-recherche"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques<\/title>\n<meta name=\"robots\" content=\"index,follow\" \/>\n<link rel=\"canonical\" href=\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\" \/>\n<meta property=\"og:description\" content=\"In this work, we are investigating the suitability of Ion Mobility Spectrometry-Mass Spectrometry (IMS) for the quantification of two isomers. A cyclic poly(L-lactide) is prepared through photodimerization of its linear homologue. ...\" \/>\n<meta property=\"og:url\" content=\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/\" \/>\n<meta property=\"og:site_name\" content=\"Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\" \/>\n<meta property=\"article:published_time\" content=\"2019-11-15T08:48:49+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2022-05-24T07:51:06+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"758\" \/>\n\t<meta property=\"og:image:height\" content=\"541\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"author\" content=\"Eric Weverbergh\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"\u00c9crit par\" \/>\n\t<meta name=\"twitter:data1\" content=\"Eric Weverbergh\" \/>\n\t<meta name=\"twitter:label2\" content=\"Dur\u00e9e de lecture estim\u00e9e\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/\",\"url\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/\",\"name\":\"New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\",\"isPartOf\":{\"@id\":\"https:\/\/web.umons.ac.be\/smos\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage\"},\"image\":{\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg\",\"datePublished\":\"2019-11-15T08:48:49+00:00\",\"dateModified\":\"2022-05-24T07:51:06+00:00\",\"author\":{\"@id\":\"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/799f9fff96a5393a6f974013d89f3782\"},\"breadcrumb\":{\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#breadcrumb\"},\"inLanguage\":\"fr-FR\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/\"]}]},{\"@type\":\"ImageObject\",\"inLanguage\":\"fr-FR\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage\",\"url\":\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg\",\"contentUrl\":\"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg\",\"width\":758,\"height\":541,\"caption\":\"New paper on the relative quantification of architectural isomeric polymers\"},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"Home\",\"item\":\"https:\/\/web.umons.ac.be\/smos\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"New paper on the relative quantification of architectural isomeric polymers\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/#website\",\"url\":\"https:\/\/web.umons.ac.be\/smos\/\",\"name\":\"Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\",\"description\":\"\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\/\/web.umons.ac.be\/smos\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"fr-FR\"},{\"@type\":\"Person\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/799f9fff96a5393a6f974013d89f3782\",\"name\":\"Eric Weverbergh\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"fr-FR\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/image\/\",\"url\":\"https:\/\/secure.gravatar.com\/avatar\/277eef236b3d46fa37342f3ff7201123ffcff78c8376e87dfb037d245a79e832?s=96&d=mm&r=g\",\"contentUrl\":\"https:\/\/secure.gravatar.com\/avatar\/277eef236b3d46fa37342f3ff7201123ffcff78c8376e87dfb037d245a79e832?s=96&d=mm&r=g\",\"caption\":\"Eric Weverbergh\"},\"url\":\"https:\/\/web.umons.ac.be\/smos\/author\/eweverbergh\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques","robots":{"index,follow":"index,follow"},"canonical":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/","og_locale":"fr_FR","og_type":"article","og_title":"New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques","og_description":"In this work, we are investigating the suitability of Ion Mobility Spectrometry-Mass Spectrometry (IMS) for the quantification of two isomers. A cyclic poly(L-lactide) is prepared through photodimerization of its linear homologue. ...","og_url":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/","og_site_name":"Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques","article_published_time":"2019-11-15T08:48:49+00:00","article_modified_time":"2022-05-24T07:51:06+00:00","og_image":[{"width":758,"height":541,"url":"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg","type":"image\/jpeg"}],"author":"Eric Weverbergh","twitter_card":"summary_large_image","twitter_misc":{"\u00c9crit par":"Eric Weverbergh","Dur\u00e9e de lecture estim\u00e9e":"1 minute"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/","url":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/","name":"New paper on the relative quantification of architectural isomeric polymers - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques","isPartOf":{"@id":"https:\/\/web.umons.ac.be\/smos\/#website"},"primaryImageOfPage":{"@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage"},"image":{"@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage"},"thumbnailUrl":"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg","datePublished":"2019-11-15T08:48:49+00:00","dateModified":"2022-05-24T07:51:06+00:00","author":{"@id":"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/799f9fff96a5393a6f974013d89f3782"},"breadcrumb":{"@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#breadcrumb"},"inLanguage":"fr-FR","potentialAction":[{"@type":"ReadAction","target":["https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/"]}]},{"@type":"ImageObject","inLanguage":"fr-FR","@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#primaryimage","url":"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg","contentUrl":"https:\/\/web.umons.ac.be\/app\/uploads\/sites\/80\/2022\/05\/2019-11-15_New-paper-on-the-relative-quantification-of-architectural-isomeric-polymers.jpg","width":758,"height":541,"caption":"New paper on the relative quantification of architectural isomeric polymers"},{"@type":"BreadcrumbList","@id":"https:\/\/web.umons.ac.be\/smos\/2019\/11\/15\/new-paper-on-the-relative-quantification-of-architectural-isomeric-polymers\/#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"Home","item":"https:\/\/web.umons.ac.be\/smos\/"},{"@type":"ListItem","position":2,"name":"New paper on the relative quantification of architectural isomeric polymers"}]},{"@type":"WebSite","@id":"https:\/\/web.umons.ac.be\/smos\/#website","url":"https:\/\/web.umons.ac.be\/smos\/","name":"Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques","description":"","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/web.umons.ac.be\/smos\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"fr-FR"},{"@type":"Person","@id":"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/799f9fff96a5393a6f974013d89f3782","name":"Eric Weverbergh","image":{"@type":"ImageObject","inLanguage":"fr-FR","@id":"https:\/\/web.umons.ac.be\/smos\/#\/schema\/person\/image\/","url":"https:\/\/secure.gravatar.com\/avatar\/277eef236b3d46fa37342f3ff7201123ffcff78c8376e87dfb037d245a79e832?s=96&d=mm&r=g","contentUrl":"https:\/\/secure.gravatar.com\/avatar\/277eef236b3d46fa37342f3ff7201123ffcff78c8376e87dfb037d245a79e832?s=96&d=mm&r=g","caption":"Eric Weverbergh"},"url":"https:\/\/web.umons.ac.be\/smos\/author\/eweverbergh\/"}]}},"lang":"fr","translations":{"fr":198},"pll_sync_post":[],"_links":{"self":[{"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/posts\/198","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/users\/157"}],"replies":[{"embeddable":true,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/comments?post=198"}],"version-history":[{"count":1,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/posts\/198\/revisions"}],"predecessor-version":[{"id":200,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/posts\/198\/revisions\/200"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/media\/199"}],"wp:attachment":[{"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/media?parent=198"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/categories?post=198"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/web.umons.ac.be\/smos\/wp-json\/wp\/v2\/tags?post=198"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}