{"id":204,"date":"2019-10-21T10:01:23","date_gmt":"2019-10-21T08:01:23","guid":{"rendered":"https:\/\/web.umons.ac.be\/smos\/?p=204"},"modified":"2022-05-24T10:04:22","modified_gmt":"2022-05-24T08:04:22","slug":"new-paper-in-collaboration-with-guy-koeckelberghs","status":"publish","type":"post","link":"https:\/\/web.umons.ac.be\/smos\/2019\/10\/21\/new-paper-in-collaboration-with-guy-koeckelberghs\/","title":{"rendered":"New paper in Collaboration with Guy Koeckelberghs"},"content":{"rendered":"

New just accepted paper in European Polymer Journal with our longtime collaborator Guy Koeckelberghs.<\/p>\n

\"\"
New paper in Collaboration with Guy Koeckelberghs<\/figcaption><\/figure>\n

In this article we investigate association of the Ni-catalyst during Kumada catalyst transfer condensative polymerization (KCTCP) and hypothesize that when adding a para-phenylene monomer to a living thiophene block to synthesize poly(thiophene)-b-poly(para-phenylene), an equilibrium exist between the incorporation of the para-phenylene monomer and the trapping of the Ni-catalyst by association with the thiophene block. We suggest that this equilibrium shifts toward the association with the thiophene block with increasing length of the thiophene block and that significant trapping only occurs when this block consist of several thiophene units.<\/p>\n","protected":false},"excerpt":{"rendered":"

In this article we investigate association of the Ni-catalyst during Kumada catalyst transfer condensative polymerization (KCTCP) and hypothesize that when adding a para-phenylene monomer to a living thiophene block to synthesize poly(thiophene)-b-poly(para-phenylene), an equilibrium exist between the incorporation of the para-phenylene monomer and the trapping of the Ni-catalyst by association with the thiophene block. …<\/p>\n","protected":false},"author":157,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[47],"tags":[],"class_list":["post-204","post","type-post","status-publish","format-standard","hentry","category-recherche"],"yoast_head":"\nNew paper in Collaboration with Guy Koeckelberghs - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques<\/title>\n<meta name=\"robots\" content=\"index,follow\" \/>\n<link rel=\"canonical\" href=\"https:\/\/web.umons.ac.be\/smos\/2019\/10\/21\/new-paper-in-collaboration-with-guy-koeckelberghs\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"New paper in Collaboration with Guy Koeckelberghs - Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\" \/>\n<meta property=\"og:description\" content=\"In this article we investigate association of the Ni-catalyst during Kumada catalyst transfer condensative polymerization (KCTCP) and hypothesize that when adding a para-phenylene monomer to a living thiophene block to synthesize poly(thiophene)-b-poly(para-phenylene), an equilibrium exist between the incorporation of the para-phenylene monomer and the trapping of the Ni-catalyst by association with the thiophene block. ...\" \/>\n<meta property=\"og:url\" content=\"https:\/\/web.umons.ac.be\/smos\/2019\/10\/21\/new-paper-in-collaboration-with-guy-koeckelberghs\/\" \/>\n<meta property=\"og:site_name\" content=\"Service \/ FS - Synth\u00e8se et Spectrom\u00e9trie de Masse Organiques\" \/>\n<meta property=\"article:published_time\" content=\"2019-10-21T08:01:23+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2022-05-24T08:04:22+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/s2mos.umons.ac.be\/wp-content\/uploads\/2019\/10\/article-2019-10-21.png\" \/>\n<meta name=\"author\" content=\"Eric Weverbergh\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"\u00c9crit par\" \/>\n\t<meta name=\"twitter:data1\" content=\"Eric Weverbergh\" \/>\n\t<meta name=\"twitter:label2\" content=\"Dur\u00e9e de lecture estim\u00e9e\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/web.umons.ac.be\/smos\/2019\/10\/21\/new-paper-in-collaboration-with-guy-koeckelberghs\/\",\"url\":\"https:\/\/web.umons.ac.be\/smos\/2019\/10\/21\/new-paper-in-collaboration-with-guy-koeckelberghs\/\",\"name\":\"New paper in Collaboration with Guy Koeckelberghs - 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